es una medida indirecta del calor sus unidades pueden ser °c o °f
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FÍSICA: Calor y energía térmica: Medida del calor
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Física
CALOR Y ENERGÍA TÉRMICA
Medida del calor - 2ª parte
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Aplicación de la medida del calor
a determinación de cantidades de calor con un calorímetro constituye un ejemplo de medida indirecta de una magnitud física. El calor cedido o tomado por un cuerpo se determina a partir de las medidas directas de la masa de agua del calorímetro y de sus temperaturas inicial y final.
Una pieza metálica se introduce en el interior de un calorímetro que contiene 100 g de agua a 20 ºC de temperatura. Tras alcanzar el equilibrio térmico, el termómetro del calorímetro indica una temperatura de 35,5 ºC. Se trata de determinar en joules y en calorías el valor cedido por la pieza en el proceso. (Tómese el calor específico del agua como c = 1 cal/(g · ºC) = 4,18 · 103 J/kg · K).
En virtud del principio de la conservación de la energía, la cantidad de calor Q1 que recibe el agua será igual, salvo el signo y dentro del error experimental, a la cantidad de calor Q2 cedida por la moneda, Es decir:
De acuerdo con la ecuación calorimétrica aplicada al agua se tiene:
)
Si se emplea el valor de c expresado en cal/g · ºC, la sustitución de los datos del anterior enunciado será directa:
Si se emplea el valor de c expresado en J/(kg · K), las magnitudes habrán de expresarse primero en unidades SI, y por tanto m = 1 · 10-1 kg; Ti = 293 K
Tf = 308,5 K. Sustituyendo, resulta:
La aplicación de la equivalencia entre el joule y la caloría como unidades de energía, 1 cal = 4,18 J, proporciona el mismo resultado:
Equivalente en agua de un calorímetro
Cuando un cuerpo se sumerge en el líquido de un calorímetro, una cierta cantidad de calor se cede al calorímetro o se toma de él. Es decir, además del agua, la parte interna del calorímetro como recipiente junto con sus elementos sumergidos tales como el termómetro y el agitador, también se enfrían o se calientan en el proceso de transferencia de calor que tiene lugar en su interior. La participación del calorímetro en este proceso se valora mediante el llamado equivalente en agua e. Se define como la masa de agua que tomaría o cedería la misma cantidad de calor que el calorímetro en iguales condiciones de temperatura. Cada calorímetro tiene su equivalente en agua que debe determinarse previamente a ser utilizado.
Con el propósito de reducir el error experimental en la utilización de la ecuación calorimétrica correspondiente al agua, debe considerarse la masa de ésta aumentada en una cantidad igual al equivalente e del calorímetro utilizado, lo que equivale a tomar el conjunto (agua + calorímetro) como un todo único a efectos de transferencia de calor en su interior. En tal caso la expresión del calor referida al calorímetro tomará la forma:
)
siendo T la temperatura del equilibrio.
La determinación experimental de e puede hacerse empleando un cuerpo o sustancia cuya masa, calor específico y temperatura inicial sean conocidas y situándolo en el interior del calorímetro cuyo equivalente e se desea determinar. En el equilibrio se cumplirá:
' es decir: )
ecuación cuya única incógnita e puede ser despejada y, por tanto, determinar su valor. Si el cuerpo o sustancia elegida es también agua, los cálculos se pueden simplificar bastante.
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Calorimetría indirecta
Calorimetría indirecta
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Medidor metabólico de calorimetría indirecta que mide el consumo de oxígeno (O2) y la producción de dióxido de carbono (CO2) de un sujeto que respira espontáneamente (método de dilución con campana).
La calorimetría indirecta calcula el calor que producen los organismos vivos midiendo su producción de dióxido de carbono y desechos de nitrógeno (con frecuencia amoníaco en organismos acuáticos, o urea en los terrestres), o de su consumo de oxígeno. La calorimetría indirecta es el método mediante el cual el tipo y la tasa de utilización del sustrato y el metabolismo energético se estiman a partir de las mediciones de intercambio de gases (producción de dióxido de carbono y consumo de oxígeno durante el descanso y el ejercicio en estado estacionario). Esta técnica proporciona información única, no es invasiva y se puede combinar ventajosamente con otros métodos experimentales para investigar numerosos aspectos de la asimilación de nutrientes, la termogénesis, la energía del ejercicio físico y la patogénesis de las enfermedades metabólicas.1
Índice
1 Antecedentes científicos
2 Historia
3 Métodos de recolección
4 Aplicaciones 5 Referencias 6 Enlaces externos
Antecedentes científicos[editar]
La calorimetría indirecta mide el consumo de O2 y la producción de CO2. Suponiendo que todo el oxígeno se usa para oxidar los combustibles degradables y que todo el CO2, con esta medida es posible calcular la cantidad total de energía producida. Debe quedar claro que "producción de energía" significa la conversión de la energía química libre de nutrientes en la energía química del ATP más la pérdida de algo de energía durante el proceso de oxidación.1 La calorimetría indirecta respiratoria, o calorimetría indirecta (IC) como la conocen la mayoría de los autores, es un método no invasivo y altamente preciso de tasa metabólica que tiene una tasa de error inferior al 1%.2 Tiene una alta reproducibilidad y se ha considerado un método estándar de oro.3 Este método permite estimar BEE y REE, y también permite la identificación de sustratos de energía que el cuerpo metaboliza predominantemente en un momento específico. Se basa en la medida indirecta del calor producido por la oxidación de los macronutrientes, que se estima mediante el monitoreo del consumo de oxígeno (O2) y la producción de dióxido de carbono (CO2) durante un cierto período de tiempo.4 El calorímetro tiene un colector de gas que se adapta al sujeto y un sistema que mide el volumen y las concentraciones de O2 y CO2 minuto a minuto. A través de una válvula unidireccional, el calorímetro recoge y cuantifica el volumen y la concentración de O2 inspirado y CO2 expirado por el sujeto. Después de alcanzar un volumen, el gasto de energía en reposo se calcula mediante la fórmula de Weir y los resultados se muestran en el software adjunto al sistema. Otra fórmula utilizada es:5
{\displaystyle M=VO_{2}\left({\frac {RQ-0.7}{0.3}}e_{c}+{\frac {1-RQ}{0.3}}e_{f}\right)}
donde RQ es el cociente respiratorio (relación entre el volumen de CO 2 producido y el volumen de O2 consumido),
{\displaystyle e_{c}}
es 21.13 kilojoules (5.05 kcal), el calor liberado por litro de oxígeno por la oxidación de carbohidratos, y
{\displaystyle e_{f}}
es 19.62 kilojoules (4.69 kcal), el valor de la grasa. Esto da el mismo resultado que la fórmula de Weir en RQ = 1 (quemando solo carbohidratos), y casi el mismo valor en RQ = 0.7 (quemar solo grasa). ⊅∑ ′
Historia[editar]
Antoine Lavoisier señaló en 1780 que la producción de calor se puede predecir a partir del consumo de oxígeno, mediante regresión múltiple. La teoría del balance dinámico de energía explica por qué este procedimiento es correcto. La calorimetría indirecta, tal como la conocemos, se desarrolló a principios de siglo como una aplicación de la termodinámica a la vida animal.6 Aunque el desarrollo de la calorimetría indirecta se remonta a más de 200 años, su mayor uso ha sido en las últimas dos décadas con el desarrollo de nutrición parenteral total, equipos de apoyo de nutrición interdisciplinarios y la producción de calorímetros portátiles, confiables y relativamente económicos.7
Métodos de recolección[editar]
Se pueden usar cuatro técnicas diferentes de recolección y medición de gas para realizar esta prueba:
Bolsa Douglas : los gases respiratorios expelidos se recogen en una bolsa hermética inflable.8 Después de completar cualquier prueba de Douglas, el gas recolectado debe analizarse para determinar el volumen y la composición.Canopy (dilución): la técnica de dilución se considera la tecnología estándar para la medición del gasto energético en reposo en nutrición clínica.3 La prueba dura solo unos minutos y consiste en hacer que un paciente se acueste relajado en una cama o en un cómodo sofá, con la cabeza debajo de una campana transparente conectada a una bomba, que aplica una ventilación ajustable a través de ella. El gas exhalado se diluye con el aire fresco ventilado debajo de la campana y una muestra de esta mezcla se transporta a los analizadores, a través de un tubo capilar y se analiza. Las fracciones ambientales y diluidas de O2 y CO2 se miden para una tasa de ventilación conocida, y el consumo de O2 y la producción de CO2 se determinan y se convierten en gasto de energía en reposo. 9es una medida indirecta al calor sus unidades pueden ser °c o °f ayudenme porfavor es de quimica
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Chicos, ¿alguien sabe la respuesta?